Well folks, as far as solo Neil Young sets go I'm not certain if it gets better than this. Recorded in 1992 in Chicago, this session was very similar to his famed MTV Unplugged session. And, if you're feeling adventurous, I'd say combine the two sets for an extended affair all created in the same light.
Take a gander at that setlist, listen to "Natural Beauty" (I heard a perfect echo die, Into an anonymous wall
of digital sound, Somewhere deep inside, Of my soul) and download the hell out of this. I'm not certain to the lineage but it sounds like a pristine soundboard, ugh, just absolute goodness.
Neil Young Official - Facebook - Twitter - The Treasury - Insound - 
01 Long May You Run
02 From Hank To Hendrix
03 Unknown Legend
04 Love Is A Rose
05 Pocahontas
06 Like A Hurricane
07 War Of Man
08 The Needle And The Damage Done
09 Tonight's The Night
10 One Of These Days
11 Such A Woman
12 Harvest Moon
13 Dreamin' Man
14 Natural Beauty
15 Don't Let It Bring You Down
16 Mr. Soul
17 Powderfinger
18 Sugar Mountain
19 You And Me
20 After The Gold Rush
DOWNLOAD - Neil Young - 1992-11-17 - WTTW Studios - Chicago, IL - Pt. 1
DOWNLOAD - Neil Young - 1992-11-17 - WTTW Studios - Chicago, IL - Pt. 2
DOWNLOAD - Neil Young - 1992-11-17 - WTTW Studios - Chicago, IL - Pt. 3